No, the application won't sync with the other one because there is no function for this operation, but you can export the data from the Android version to import it back to Windows version. To download the application, access the official website.
Windows version supports importing from these services/apps:
XML
Access Manager 2
Firefox Exporter
KeePass2
Ultrasoft Datashield
Handy Safe Pro
SafeWallet
CSV
OI Safe
Dataviz Passwords Plus
SplashID (VID2 and VID3)
Ascendo Datavault
WhisperSync