No, you can't purchase the CD of Hoyle Card Games 2012 for the 64bit because the software isn't listed as a 64bit compatible application. It works for newer versions of Windows, but that's it. Also, you can't purchase a CD because the Hoyle Gaming (developers of this game) list it as a download only product.
I suggest you visit their official website to check for alternatives that run in 64bit Windows versions.
