No, this version that you have is not and will never be compatible with Windows 10. According to various compatibility info, PrintMaster Gold 12 is developed to run on the following versions of Windows: Windows 98, Windows Me, Windows 95. As you can see this version that you have is very old and doesn't have support for Windows 10.
There is another version of PrintMaster released on Broderbund website that is compatible with the latest versions of Windows. You can obtain additional information through the following link: http://www.broderbund.com/p-860-printmaster-v7-platinum.aspx