No, the software won't work with Windows 10. I have checked the Western Digital website and found out that the tools require the following Windows version to be installed in order to work properly.
- Windows XP with SP3
- Windows Vista with SP2
- Windows 7 with SP1
- Windows 8
Since this is an application that works with hard drives, I wouldn't recommend using it on an unsupported operating system.
Official website: http://support.wdc.com/downloads.aspx?p=206&lang=en