From the moment you select Convert and Burn, a window opens asking what type of CD/DVD you want to create. Once the type is selected, another window opens asking you to choose the CD/DVD-Rom drive. Add the files that you want to transfer on CD/DVD, then choose the burning speed and that's it. If no CD/DVD-Rom drive appears in the list, then it means there is something wrong with it and Windows is not detecting it.
For more information, visit the official website: http://www.effectmatrix.com/total-video-converter/guide/burn-video-to-vcd.htm