How to convert pdf to kml kmz?

you can use software (gpsexpert) to convert kml or kmz to dxf then open it by autocad then you can save it as dwg or plot it as pdf  

... to convert the KML or KMZ to CSV, and converting from CSV to PDF or ... Internet that let you convert CSV to PDF/DWG ). Another way ... printable file. Just google "virtual pdf printer" and you'll find ...