Yes. This can be done using Import function and WIA service (Windows Image Acquisition). To perform this, open the program, go to File > Import > WIA Support, choose a destination for your image, make sure that Open Acquired Images in Photoshop option is selected and click Start. From there you need to select the webcam, take the picture, select it and click Get Picture. For additional information about this matter, you can check the following support website.