There are no hidden settings in the application to copy your DVDs, but if the DVDs are heavily protected, then copying them won't work because you need to bypass decryption. Luckily, there are applications of this kind available on the Internet.
There is an application called DVDDecrypter that can help you decrypt the DVD: http://dvddecrypter.software.informer.com/
Note: Always use the application for personal use.