Try using Revo Uninstaller. Even if it can't uninstall the application normally, it will force it to uninstall by wiping out all traces of its presence from the system.
After that, try running AdwCleaner to make sure that there are no leftover rogue registry keys or toolbars in your system.
AdwCleaner will make sure the pop-ups will be removed. Run it two times in a row to remove the application completely from your browser.