To enable Wake-On-Lan feature, go to Options using Extras > Options. On the General tab, locate the Wake-On-LAN feature and click Configure. This option requires attaching the PC to your account. Now you have the possibility to Wake-On-Lan using another ID or a web address.
There is also a manual of the Wake-On-Lan function available for downloading: http://www.teamviewer.com/link/?url=141508