Yes, Free Video Decompiler extracts multiple pictures at the same time from a video file. The tool can get every frame in the video and save it as an image or save a picture every 10, 20 or 30 frames.
Also, a word of warning: according to VirusTotal, the application may be infected with some kind of malware or PUP, so I recommend running it in a sandbox tool like Sandboxie, to keep your system safe.
